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Silver‐Catalyzed Carbene Functionalization of Methane in Supercritical Carbon Dioxide
Author(s) -
Doyle Michael P.
Publication year - 2011
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201100228
Subject(s) - carbene , ethyl diazoacetate , methane , supercritical fluid , surface modification , catalysis , hydrocarbon , chemistry , supercritical carbon dioxide , hydrogen , photochemistry , organic chemistry , cyclopropanation
Supercritical, methane? It is insertion! Carbon–hydrogen insertion occurs between the least reactive hydrocarbon, methane, and the carbene intermediate formed from ethyl diazoacetate.