Au on Nanosized NiO: A Cooperative Effect between Au and Nanosized NiO in the Base‐Free Alcohol Oxidation | Zendy

Villa Alberto | Zendy; ChanThaw Carine E. | Zendy; Veith Gabriel M. | Zendy; More Karren L. | Zendy; Ferri Davide | Zendy; Prati Laura | Zendy

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Au on Nanosized NiO: A Cooperative Effect between Au and Nanosized NiO in the Base‐Free Alcohol Oxidation

Author(s) -

Villa Alberto,

ChanThaw Carine E.,

Veith Gabriel M.,

More Karren L.,

Ferri Davide,

Prati Laura

Publication year - 2011

Publication title -

chemcatchem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.497

H-Index - 106

eISSN - 1867-3899

pISSN - 1867-3880

DOI - 10.1002/cctc.201100161

Subject(s) - non blocking i/o , polyvinyl alcohol , catalysis , alcohol oxidation , nanoparticle , materials science , base (topology) , chemical engineering , alcohol , chemistry , nanotechnology , organic chemistry , mathematical analysis , mathematics , engineering , composite material

Nanosized NiO has been synthesized and used as a support for polyvinyl alcohol‐protected Au nanoparticles. This catalytic system exhibits an extraordinary performance in the base‐free liquid phase oxidation of alcohols compared to the same Au supported on a commercial, micrometersized NiO. This enhancement in activity cannot be solely attributed to the improved basic properties of the support. A cooperative effect between Au nanoparticles and nanosized NiO is envisaged.

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