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Interlayer‐Expanded Microporous Titanosilicate Catalysts with Functionalized Hydroxyl Groups
Author(s) -
Xiao FengShou,
Xie Bin,
Zhang Haiyan,
Wang Liang,
Meng Xiangju,
Zhang Weiping,
Bao Xinhe,
Yilmaz Bilge,
Müller Ulrich,
Gies Hermann,
Imai Hiroyuki,
Tatsumi Takashi,
De Vos Dirk
Publication year - 2011
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201100144
Subject(s) - microporous material , calcination , catalysis , chemistry , group (periodic table) , chemical engineering , organic chemistry , materials science , engineering
Simple as that: A novel crystalline microporous titanosilicate (Ti‐COE‐4) with functionalized hydroxyl groups and medium micropore size (0.55 nm) is successfully synthesized through dimethylsilylation and calcination. The synergism of hydroxyl groups with active Ti sites in Ti‐COE‐4 significantly improves its catalytic activities in oxidation reactions.