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High‐Selectivity Hydrogenation of Chloronitrobenzene to Chloroaniline Over Magnesium Fluoride‐Supported Bimetallic Ruthenium‐Copper Catalysts
Author(s) -
Pietrowski Mariusz,
Zieliński Michał,
Wojciechowska Maria
Publication year - 2011
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201100009
Subject(s) - bimetallic strip , ruthenium , selectivity , aniline , catalysis , copper , magnesium , chemistry , inorganic chemistry , combinatorial chemistry , organic chemistry
An aniline exclusive : The introduction of copper to a Ru/MgF 2 catalyst results in the strong inhibition of the side reaction of hydrodechlorination during the hydrogenation of ortho ‐chloronitrobenzene and allows ortho ‐chloroaniline to be produced at 100 % selectivity.