Stereoselective Palladium Catalyzed Allylic Phosphination | Zendy

Duraud Amélie | Zendy; Jacquet Olivier | Zendy; Fiaud JeanClaude | Zendy; Guillot Régis | Zendy; Toffano Martial | Zendy

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Stereoselective Palladium Catalyzed Allylic Phosphination

Author(s) -

Duraud Amélie,

Jacquet Olivier,

Fiaud JeanClaude,

Guillot Régis,

Toffano Martial

Publication year - 2011

Publication title -

chemcatchem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.497

H-Index - 106

eISSN - 1867-3899

pISSN - 1867-3880

DOI - 10.1002/cctc.201000458

Subject(s) - enantiopure drug , palladium , allylic rearrangement , nucleophile , chemistry , stereoselectivity , borane , phosphine , catalysis , medicinal chemistry , ligand (biochemistry) , stereocenter , stereochemistry , enantioselective synthesis , combinatorial chemistry , organic chemistry , biochemistry , receptor

Chiral enantiopure 2‐5‐diphenylphospholane borane 8 is an interesting nucleophile for allylic phosphination in the presence of palladium complexes to form CP bonds. A highly diastereoselective allylic phosphination reaction was realized using chiral palladium‐DACH‐naphthyl (DACH=1,2‐diaminocyclohexane) ligand as the catalyst system. The secondary phosphine‐borane complex could be classified as a Nu L type nucleophile.

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