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Selective Debenzylation of Benzyl Protected Groups with Silia Cat Pd(0) under Mild Conditions
Author(s) -
Pandarus Valerica,
Béland François,
Ciriminna Rosaria,
Pagliaro Mario
Publication year - 2011
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201000420
Subject(s) - yield (engineering) , catalysis , chemistry , palladium , aryl , medicinal chemistry , organic chemistry , materials science , alkyl , metallurgy
A catalyst in the crowd: The selective debenzylation of aryl benzyl ethers, benzyl esters, and benzyl amines leaving other sensitive groups intact can be carried out in high yield under remarkably mild conditions [0.1 MPa (1 bar), H 2 at room temperature] over a new series of recyclable palladium(0) heterogeneous catalysts.