Premium
CO+NO versus CO+O 2 Reaction on Monolayer FeO(111) Films on Pt(111)
Author(s) -
Lei Yu,
Lewandowski Mikolaj,
Sun YingNa,
Fujimori Yuichi,
Martynova Yulija,
Groot Irene M. N.,
Meyer Randall J.,
Giordano Livia,
Pacchioni Gianfranco,
Goniakowski Jacek,
Noguera Claudine,
Shaikhutdinov Shamil,
Freund HansJoachim
Publication year - 2011
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201000388
Subject(s) - monolayer , limiting , oxygen , materials science , catalysis , chemistry , crystallography , nanotechnology , organic chemistry , mechanical engineering , engineering
Caught on film: NO exposed to monolayer FeO(111) film grown on Pt(111) at elevated pressures readily forms a trilayer OFeO film that is virtually identical to that formed with O 2 . However, CO 2 production in the CO+NO reaction is negligible as compared to CO+O 2 , which is rationalized in terms of the replenishment of oxygen vacancies as the rate‐limiting step that proceeds much faster with O 2 than NO.