Enantioselective Intramolecular Hydroamination of Secondary Amines Catalyzed by Easily Accessible Ate and Neutral Rare‐Earth Complexes | Zendy

Queffelec Clémence | Zendy; Boeda Fabien | Zendy; Pouilhès Annie | Zendy; Meddour Abdelkrim | Zendy; Kouklovsky Cyrille | Zendy; Hannedouche Jérôme | Zendy; Collin Jacqueline | Zendy; Schulz Emmanuelle | Zendy

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Enantioselective Intramolecular Hydroamination of Secondary Amines Catalyzed by Easily Accessible Ate and Neutral Rare‐Earth Complexes

Author(s) -

Queffelec Clémence,

Boeda Fabien,

Pouilhès Annie,

Meddour Abdelkrim,

Kouklovsky Cyrille,

Hannedouche Jérôme,

Collin Jacqueline,

Schulz Emmanuelle

Publication year - 2011

Publication title -

chemcatchem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.497

H-Index - 106

eISSN - 1867-3899

pISSN - 1867-3880

DOI - 10.1002/cctc.201000323

Subject(s) - hydroamination , enantioselective synthesis , chemistry , ytterbium , rare earth , enantiomer , yttrium , intramolecular force , catalysis , enantiomeric excess , amine gas treating , iridium , combinatorial chemistry , organic chemistry , medicinal chemistry , materials science , doping , mineralogy , oxide , optoelectronics

The magnificent neutral: Secondary amines are cyclized into the corresponding scalemic pyrrolidines and piperidines with in situ‐prepared chiral alkylamido ate and neutral yttrium and ytterbium catalysts. The enantiomeric excess of 83 % ee is the highest reported value for a rare‐earth‐promoted hydroamination of a secondary amine.

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