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Iron‐Catalyzed Reductive Aryl–Alkenyl Cross‐Coupling Reactions
Author(s) -
Czaplik Waldemar M.,
Mayer Matthias,
Jacobi von Wangelin Axel
Publication year - 2011
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201000276
Subject(s) - aryl , catalysis , coupling reaction , chemistry , coupling (piping) , reductive elimination , homogeneous catalysis , photochemistry , combinatorial chemistry , organic chemistry , materials science , alkyl , metallurgy
Direct and to the point: The simple precatalyst system FeCl 3 /TMEDA has been effectively applied to cross‐coupling reactions of various arylmagnesium bromides and alkenyl bromides. With activated aryl bromides and in the absence of polar functional groups, the method can be modified to allow for domino iron‐catalyzed magnesiation–cross‐coupling reactions.