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Ultra‐Low‐Temperature Water–Gas Shift Catalysis using Supported Ionic Liquid Phase (SILP) Materials*
Author(s) -
Werner Sebastian,
Szesni Normen,
Kaiser Melanie,
Fischer Richard W.,
Haumann Marco,
Wasserscheid Peter
Publication year - 2010
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201000245
Subject(s) - ionic liquid , water gas shift reaction , catalysis , hydrogen , gas phase , robustness (evolution) , chemistry , phase (matter) , chemical engineering , ionic bonding , inorganic chemistry , materials science , organic chemistry , ion , engineering , biochemistry , gene
SILP inside the eye of your mind: A new class of water–gas shift catalyst system that outperforms commercial shift catalysts under ultra‐low‐temperature real gas conditions ( T <160 °C) has been developed. The new catalysts consist of [{RuCl 2 (CO) 3 } 2 ] dissolved in a chloride ionic liquid and dispersed on a porous basic support using the SILP approach. Its robustness and recyclability make it highly attractive for industrial hydrogen production.