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Facile Synthesis of Mesoporous Magnetic Nanocomposites and their Catalytic Application in Carbon–Carbon Coupling Reactions
Author(s) -
Shylesh Sankaranarayanapillai,
Wang Lei,
Demeshko Serhiy,
Thiel Werner R.
Publication year - 2010
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201000215
Subject(s) - nanocomposite , catalysis , materials science , mesoporous material , palladium , mesoporous silica , grafting , coupling reaction , carbon fibers , coupling (piping) , chemical engineering , mesoporous organosilica , nanoparticle , nanotechnology , chemistry , organic chemistry , composite number , composite material , polymer , engineering
A ‘bottom‐up’ approach is utilized for assembling magnetic nanoparticles in a mesoporous silica solid for the generation of a magnetic nanocomposite. Grafting of a palladium complex of the type (L) 2 PdCl 2 (L=Si(OMe) 3 functionalized PPh 3 ) results in an active, recyclable catalyst for CC coupling reactions.