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[Cu 3 (BTC) 2 ]: A Metal–Organic Framework Catalyst for the Friedländer Reaction
Author(s) -
PérezMayoral Elena,
Čejka Jiří
Publication year - 2011
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201000201
Subject(s) - acetylacetone , catalysis , metal organic framework , lewis acids and bases , chemistry , reaction conditions , metal , heterogeneous catalysis , organic chemistry , adsorption
Länder the Fried, home of the MOF: Basolite C 300, a metal–organic framework exhibiting a hard Lewis acid character, is found to be the first efficient MOF catalyst for the Friedländer reaction between 2‐aminobenzophenones and acetylacetone under mild reaction conditions, leading to the corresponding quinolines with excellent yields, opening the door towards its utilization for analogous condensations leading to useful biologically active compounds.