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Mechanoassisted Supramolecular Catalysis in Solid State Synthesis
Author(s) -
Ma DaYou,
Wärnmark Kenneth
Publication year - 2010
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201000150
Subject(s) - supramolecular chemistry , catalysis , supramolecular catalysis , stereospecificity , solid state , grinding , ethylene , chemistry , combinatorial chemistry , materials science , organic chemistry , molecule , composite material
Higher ground: Stereospecific and quantitative [2+2] photodimerization of trans ‐1,2‐bis(4‐pyridyl)ethylene in solid state is effectively catalyzed by 4,6‐ dichlororesorcinol in a supramolecular fashion. Grinding is the crucial process to drive the catalytic cycles.