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Catalytic Addition of Aromatic CH Bonds to Vinylsilanes in the Presence of Ru/CeO 2
Author(s) -
Miura Hiroki,
Wada Kenji,
Hosokawa Saburo,
Inoue Masashi
Publication year - 2010
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201000144
Subject(s) - catalysis , chemistry , solvent , atmosphere (unit) , turnover number , organic chemistry , photochemistry , polymer chemistry , physics , thermodynamics
Special addition: The addition of aromatic CH bonds to vinylsilanes proceeds smoothly in the presence of Ru/CeO 2 . The choice of appropriate additive realizes catalysis on the solid surface. This catalytic reaction can be carried out without solvent on a large scale to achieve a high turnover number. Modification of Ru/CeO 2 with PPh 3 under a H 2 atmosphere markedly increases the catalytic activity.
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