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Synthesis of a Bioxazoline‐Derived Ru Metathesis Catalyst
Author(s) -
Vehlow Kati,
Porta Marta,
Blechert Siegfried
Publication year - 2010
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.201000138
Subject(s) - carbene , ligand (biochemistry) , catalysis , steric effects , ruthenium , metathesis , olefin metathesis , chemistry , combinatorial chemistry , acyclic diene metathesis , ring opening metathesis polymerisation , salt metathesis reaction , organic chemistry , polymerization , receptor , biochemistry , polymer
As ligand has it… A new class of ruthenium catalyst based on a bioxazoline‐derived N‐heterocyclic carbene (IBioxNHC) ligand has been synthesized that exhibits high stability at elevated temperatures and is a suitable catalyst for olefin metathesis. A slow initiation rate, owing to the steric hindrance of the NHC ligand, may be of interest for certain metathesis applications.