Aerobic Oxidative Dehydrogenation of 2‐Substituted Imidazolines Promoted by a Cyclometalated Ruthenium Catalyst | Zendy

Taketoshi Ayako | Zendy; Tsujimoto Akitsu | Zendy; Maeda Shusaku | Zendy; Koizumi Takeaki | Zendy; Kanbara Takaki | Zendy

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Aerobic Oxidative Dehydrogenation of 2‐Substituted Imidazolines Promoted by a Cyclometalated Ruthenium Catalyst

Author(s) -

Taketoshi Ayako,

Tsujimoto Akitsu,

Maeda Shusaku,

Koizumi Takeaki,

Kanbara Takaki

Publication year - 2010

Publication title -

chemcatchem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.497

H-Index - 106

eISSN - 1867-3899

pISSN - 1867-3880

DOI - 10.1002/cctc.200900251

Subject(s) - dehydrogenation , ruthenium , catalysis , oxidative phosphorylation , homogeneous , chemistry , homogeneous catalysis , combinatorial chemistry , organic chemistry , photochemistry , biochemistry , physics , thermodynamics

Complex answer to a simple question: The aerobic oxidative dehydrogenation of 2‐substituted imidazolines to their corresponding imidazoles has been achieved. A cyclometalated homogeneous Ru III complex, [RuCl(ppy)(tpy)][PF 6 ] (see scheme), worked as a catalyst under mild conditions without the need for a co‐oxidant.

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