Rhodium‐Catalyzed Decarbonylative Coupling Reactions of Diphenylketene with Alkenes | Zendy

Kondo Teruyuki | Zendy; Tokoro Yukiko | Zendy; Ura Yasuyuki | Zendy; Wada Kenji | Zendy; Mitsudo Takeaki | Zendy

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Rhodium‐Catalyzed Decarbonylative Coupling Reactions of Diphenylketene with Alkenes

Author(s) -

Kondo Teruyuki,

Tokoro Yukiko,

Ura Yasuyuki,

Wada Kenji,

Mitsudo Takeaki

Publication year - 2009

Publication title -

chemcatchem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.497

H-Index - 106

eISSN - 1867-3899

pISSN - 1867-3880

DOI - 10.1002/cctc.200900075

Subject(s) - cyclopropane , rhodium , chemistry , decarbonylation , toluene , catalysis , octane , norbornene , coupling reaction , alkene , photochemistry , medicinal chemistry , organic chemistry , ring (chemistry) , polymer , monomer

The decarbonylative coupling reaction of diphenylketene with 2‐norbornene, catalyzed by [{RhCl(CO) 2 } 2 ], proceeds smoothly in toluene to give the corresponding substituted cyclopropane, 3,3‐diphenyltricyclo[3.2.1.0 2, 4 ]octane, in good yield. The corresponding reaction of diphenylketene with electron‐deficient terminal alkenes leads to the linear coupling products.

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