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Organic–Inorganic Hybrid Materials for Enantioselective Organocatalysis
Author(s) -
Srivastava Vivek,
Gaubert Kevin,
Pucheault Mathieu,
Vaultier Michel
Publication year - 2009
Publication title -
chemcatchem
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.497
H-Index - 106
eISSN - 1867-3899
pISSN - 1867-3880
DOI - 10.1002/cctc.200900035
Subject(s) - organocatalysis , enantioselective synthesis , chemistry , catalysis , ammonium , organic chemistry , hybrid material , metal organic framework , adsorption
State of clay : Chiral organic–inorganic hybrid materials based on amino acid‐exchanged clays are prepared and used for heterogeneous asymmetric organocatalysis. Co‐inclusion of ammonium cations within interlayers greatly enhances yields and selectivities. Recyclability of the material is evaluated, showing no decrease in enantioselectivity or conversion after ten cycles.