Unexpected Puckering of Hydroxyproline in the Guest Triplets, Hyp‐Pro‐Gly and Pro‐alloHyp‐Gly Sandwiched between Pro‐Pro‐Gly Sequence | Zendy

Jiravanichanun Nattha | Zendy; Hongo Chizuru | Zendy; Wu Guanghan | Zendy; Noguchi Keiichi | Zendy; Okuyama Kenji | Zendy; Nishino Norikazu | Zendy; Silva Teresita | Zendy

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Unexpected Puckering of Hydroxyproline in the Guest Triplets, Hyp‐Pro‐Gly and Pro‐alloHyp‐Gly Sandwiched between Pro‐Pro‐Gly Sequence

Author(s) -

Jiravanichanun Nattha,

Hongo Chizuru,

Wu Guanghan,

Noguchi Keiichi,

Okuyama Kenji,

Nishino Norikazu,

Silva Teresita

Publication year - 2005

Publication title -

chembiochem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.05

H-Index - 126

eISSN - 1439-7633

pISSN - 1439-4227

DOI - 10.1002/cbic.200500055

Subject(s) - hydroxyproline , diastereomer , chemistry , proline , position (finance) , sequence (biology) , stereochemistry , ring (chemistry) , selectivity , crystallography , resolution (logic) , biochemistry , amino acid , organic chemistry , finance , artificial intelligence , computer science , economics , catalysis

The ups and downs . High‐resolution X‐ray data revealed interesting proline ring puckering of hydroxyproline diastereoisomers, which could be in an atypical state depending on position selectivity. AlloHyp at the Y position in one sequence showed up‐puckering (left), while Hyp at the X position in another showed down‐puckering (right). On the other hand, Hyp at the Y position showed up‐puckering as expected.

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