Residue‐ and Sequence‐Selective Binding of Nonaromatic Dipeptides by Bis(β‐cyclodextrin) with a Functional Tether | Zendy

Liu Yu | Zendy; Yang YingWei | Zendy; Song Yun | Zendy; Zhang HengYi | Zendy; Ding Fei | Zendy; Wada Takehiko | Zendy; Inoue Yoshihisa | Zendy

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Residue‐ and Sequence‐Selective Binding of Nonaromatic Dipeptides by Bis(β‐cyclodextrin) with a Functional Tether

Author(s) -

Liu Yu,

Yang YingWei,

Song Yun,

Zhang HengYi,

Ding Fei,

Wada Takehiko,

Inoue Yoshihisa

Publication year - 2004

Publication title -

chembiochem

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.05

H-Index - 126

eISSN - 1439-7633

pISSN - 1439-4227

DOI - 10.1002/cbic.200300770

Subject(s) - cyclodextrin , chemistry , residue (chemistry) , selectivity , peptide , sequence (biology) , stereochemistry , organic chemistry , biochemistry , catalysis

Do you recognise this peptide? Novel 6,6′‐(2,2′‐dithiobis(2‐(benzoylamino)ethylamino))‐bridged bis(β‐CD), such as the one shown here, showed good to excellent residue selectivities of up to 28 for several nonaromatic dipeptides with the complex stability sequence of Glu‐Glu < Gly‐Gly < Leu‐Gly < Met‐Met < Gly‐Pro < Gly‐Leu, and also a high sequence selectivity of 5.0 for Gly‐Leu versus Leu‐Gly.

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