A Monomeric Bis(arena)lead( II ) Complex with a Plumbocene‐like Bent Sandwich Structural Unit — Structure of [Pb(1,2‐C 6 H 4 Me 2 ) 2 (AlCl 4 ) 2 | Zendy

Frank Walter | Zendy; Wittmer FranzGeorg | Zendy

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A Monomeric Bis(arena)lead( II ) Complex with a Plumbocene‐like Bent Sandwich Structural Unit — Structure of [Pb(1,2‐C 6 H 4 Me 2 ) 2 (AlCl 4 ) 2

Author(s) -

Frank Walter,

Wittmer FranzGeorg

Publication year - 1997

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19971301204

Subject(s) - chemistry , monomer , denticity , iodide , crystallography , stereochemistry , crystal structure , chloride , polymer chemistry , inorganic chemistry , organic chemistry , polymer

Bis( o ‐xylene)lead(II) bis(tetrachloroaluminate), obtained from lead(II) chloride and aluminium trichloride in o ‐xylene, has been shown by X‐ray crystallography to be a mononuclear lead complex with point group symmetry C 2 The two aromatic ligands are arranged similarly to those in monomeric plumbocene. The coordination sphere is completed by two bidentate AlCl 4 − ions. The lead center uses about a quarter of its bonding capability for each of the four ligands

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