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Synthesis and Structure of Trimethyllead Niobocene Dihydride
Author(s) -
Nikonov Georgii, I.,
Avtomonov Evgeni V.,
Massa Werner
Publication year - 1997
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19971301112
Subject(s) - chemistry , hydride , amine gas treating , stereochemistry , nuclear magnetic resonance spectroscopy , medicinal chemistry , organic chemistry , hydrogen
The reaction of niobocene trihydride [Cp 2 NbH 3 ] with ClPbMe 3 in the presence of amine affords the plumbido dihydride complex [Cp 2 NbH 2 (PbMe 3 )] ( 1 ). Compound 1 represents the first example of a stable complex with neighbouring hydride and terminal plumbyl substituents. The structure of this compound has been established by NMR and IR spectroscopy and confirmed by an X‐ray structure analysis.