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Hydrocarbon‐Bridged Complexes, XL. Polyene‐Bridged Iridium(III), Palladium(II), and Platinum(II) Complexes of Schiff Bases from α,ω‐Polyene Dialdehydes and α‐Amino Acids or o ‐Aminophenol
Author(s) -
Fehn Armin,
Briel Oliver,
Beck Wolfgang
Publication year - 1997
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19971301018
Subject(s) - polyene , chemistry , iridium , palladium , platinum , polymer chemistry , schiff base , medicinal chemistry , stereochemistry , catalysis , organic chemistry
Schiff bases 1 11 were synthesized from α‐amino acids or o‐aminophenol and crocetindialdehyde, 2,7‐dimethyloctatrienedial, terephthalaldehyde, or β,β′ ‐p‐phenylendiacroleine. The reactions of these Schiff bases with chloro‐bridged complexes [(R 3 P)(Cl)M(η‐Cl)] 2 (M = Pd, Pt) and [(C 5 Me 5 )(Cl)Ir(°Cl)] 2 gave the dinuclear complexes 12 – 31 .