Premium
Synthesis and Crystal Structure of tert ‐Butylamino)di‐ tert ‐butyl)siliceniotrichloroaluminate, (Me 3 C) 2 SiNCMe 3 ·AlCl 3 , and Dimethylazomethine‐Aluminium Trichloride, Me 2 CNH·AlCl 3
Author(s) -
Klingebiel Uwe,
Noltemyer Mathias,
Schmidt HansGeorg,
SchmidtBäse Dieter
Publication year - 1997
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19971300613
Subject(s) - chemistry , adduct , boron trichloride , crystal structure , ether , medicinal chemistry , aluminium , diethyl ether , stereochemistry , crystallography , organic chemistry , boron
Lithiated text ‐butylaminolfluorosilanes react with aluminum trichloride in ether, eliminating LiF to give AlCl 3 adducts of iminosilanes — aminosiliceniotrichloroaluminates {R 2 Si‐NCMe 3 ·AlCl 3 }, which thermally form the dimethylazomethine‐ aluminium trichloride, Me 2 CNH·AlCl 3 .