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Atropisomeric Binaphthalene‐Core Phosphacyclic Derivatives in Coordination Chemistry and Homogeneous Catalysis
Author(s) -
Gladiali Serafino,
Fabbri Davide
Publication year - 1997
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19971300503
Subject(s) - chemistry , catalysis , homogeneous catalysis , homogeneous , coordination complex , core (optical fiber) , combinatorial chemistry , enantioselective synthesis , stereochemistry , atropisomer , computational chemistry , organic chemistry , physics , materials science , composite material , thermodynamics , metal
Binaphthophospholes and binaphthophosphepines have recently been synthesized. These are the first representatives of a new class of chiral ligands that include within the same structure an endocyclic phosphorus donor, a local C 2 symmetry and an axially chiral core. In this review we discuss the synthesis, chemical behaviour and first applications in asymmetric catalysis of these novel derivatives.