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Chiral Organometallic Reagents XXI. Stereoselective Carbenoid Cyclization Reactions
Author(s) -
Stiasny Hans Christian,
Böhm Volker P. W.,
Hoffmann Reinhard W.
Publication year - 1997
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19971300307
Subject(s) - carbenoid , cyclopropanation , chemistry , intramolecular force , aldehyde , stereoselectivity , reagent , stereochemistry , organic chemistry , catalysis , rhodium
The dichotomy between concerted cyclopropanation and carbolithiation pathways on intramolecular carbenoid cyclopropanation reactions has been studied. These studies have been extended to the intramolecular carbenoid/aldehyde addition reaction.