Silver Chloroacetate: Crystal Structure and Thermal Polymerization Mechanism | Zendy

Epple Matthias | Zendy; Kirschnick Holger | Zendy

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Silver Chloroacetate: Crystal Structure and Thermal Polymerization Mechanism

Author(s) -

Epple Matthias,

Kirschnick Holger

Publication year - 1997

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19971300224

Subject(s) - chemistry , crystal structure , polymerization , solid state , salt (chemistry) , metal , polymer chemistry , chloride , crystallography , thermal analysis , thermal , organic chemistry , polymer , thermodynamics , physics

The structure of silver chloroacetate was determined by single‐crystal X‐ray structure analysis. This represents the first salt of a monohalogenoacetic acid with a monovalent metal whose structure was determined with high precision. The salt undergoes a thermally induced solid‐state polymerization to polyglycolide under elimination of silver chloride. A probable mechanism for a structure‐determined reaction in the solid state is discussed.

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