Polygold(1‐adamantyl)ammonium Salts | Zendy

LópezDeLuzuriage José M. | Zendy; Schier Annette | Zendy; Schmidbaur Hubert | Zendy

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Polygold(1‐adamantyl)ammonium Salts

Author(s) -

LópezDeLuzuriage José M.,

Schier Annette,

Schmidbaur Hubert

Publication year - 1997

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19971300213

Subject(s) - tetrafluoroborate , oxonium ion , chemistry , ammonium , medicinal chemistry , tris , crystal structure , crystallography , organic chemistry , ion , ionic liquid , catalysis , biochemistry

The reaction of 1‐adamantylamine with tris(triphenylphosphaneaurio)oxonium tetrafluoroborate results in the formation of the trinuclear adamantyltris(triphenylphosphaneaurio)ammonium tetrafluoroborate {C 10 H 15 [Au(PPh 3 )] 3 } + BF 4 − . The product can be further aurated by addition of equimolar amounts of triphenylphosphanegold(I) tetrafluoroborate to give the tetranuclear complex {C 10 H 15 N[Au(PPh 3 )] 4 } 2+ (BF 4 minus; ) 2 . Both compounds have been fully characterized by analytical and spectroscopic data, and in the case of the trinuclear complex by a single crystal X‐ray structure determination.

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