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Sulfenato, Thiosulfinato, and Thiosulfonato Transition Metal Complexes
Author(s) -
Weigand Wolfgang,
Wünsch Ralf
Publication year - 1996
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19961291202
Subject(s) - chemistry , platinum , medicinal chemistry , sulfur , moiety , phthalimides , oxidative addition , transition metal , ruthenium , yield (engineering) , stereochemistry , organic chemistry , catalysis , phthalimide , materials science , metallurgy
The synthesis and coordination chemistry of sulfenic, thiosulfinic, and thiosulfonic acid anions are reviewed. Different approaches, which yield the platinum(II) and ruthenium(II) complexes containing the anionic sulfur(0), sulfur(II), and sulfur(IV) oxid ligands, are described. The oxidative addition of thiosulfinates or N ‐sulfinyl phthalimides to platinum(0) complexes L 2 Pt(C 2 H 4 ) [L = PPh 3 , 1/2 PPh 2 CH 2 CH 2 PPh 2 , 1/2 ( R,R )‐(–)‐DIOP, 1/2 (C 5 H 4 PPh 2 )Fe(C 5 H 4 PPh 2 ) leads to sulfenato complexes; those of N ‐thiosulfinyl phthalimidies or trisulfid 1‐oxides afford the thiosulfinato complexes. Moreover, the reactions of CpRu(PPh 3 )(L)(SH) (L = CO, PPh 3 ) with N ‐sulfinyl phthalimides forming the thiosulfinato moiety, are reported. The spectroscopic, structural and chemical properties of these complexes are discussed.