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A Palladium‐Catalyzed Domino Coupling Process Leading to Annelated Pentafulvenes
Author(s) -
Dyker Gerald,
Nerenz F.,
Siemsen P.,
Bubenitschek P.,
Jones Peter G.
Publication year - 1996
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19961291019
Subject(s) - chemistry , domino , palladium , catalysis , aryl , coupling (piping) , combinatorial chemistry , process (computing) , key (lock) , medicinal chemistry , organic chemistry , mechanical engineering , alkyl , computer science , engineering , operating system , ecology , biology
Annelated pentafulvenes 2, 10, 13 , and 14 are efficiently accessible by a palladium‐catalyzed domino coupling process of aryl substituted vinylic bromides 1, 9, 11 , and 12 , 5‐Membered palladacycles 3 are discussed as key intermediates.