Structural Studies on Indium and Tin Thiobenzoates | Zendy

Singh P. | Zendy; Gupta Vishnu D. | Zendy; Bhattacharya S. | Zendy; Nöth Heinrich | Zendy

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Structural Studies on Indium and Tin Thiobenzoates

Author(s) -

Singh P.,

Gupta Vishnu D.,

Bhattacharya S.,

Nöth Heinrich

Publication year - 1996

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19961290918

Subject(s) - chemistry , indium , tin , octahedron , crystallography , tris , atom (system on chip) , x ray crystallography , crystal structure , stereochemistry , diffraction , organic chemistry , biochemistry , physics , computer science , optics , embedded system

Indium(III) and tin(IV) thiocarboxylates were prepared and characterized on the basis of their IR, 13 C‐ and 19 Sn‐NMR data. Indium tris(thiobenzoate) ( 1 ) decomposes into a sulfido complex In (S)[S(O)CPh] ( 2a ). The corresponding tris(thioacetate) In[S(O)CMe] 3 is thermally too unstable to be isolated. The anionic tetrakis complex [Et 3 NH]{In[S(O)CPh] 4 } ( 3 ) was characterized by X‐ray crystallography which revealed a distorted tetrahedral coordination at the In atom. X‐ray diffraction analysis of the complexes BuSn[S(O)CPh] 3 ( 4 ) and Cl 2 Sn[S(O)CPh] 2 ( 7 ) showed distorted tetrahedral and cis ‐octahedral structures, respectively.

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