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Zirconium Species as Tools in Phosphorus Chemistry, 1 [Cp 2 ZrHCI] n , a Versatile Reagent
Author(s) -
Majoral JeanPierre,
Zablocka Maria,
Igau Alain,
Cénac Nathalie
Publication year - 1996
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19961290802
Subject(s) - chemistry , reagent , phosphorus , zirconium , ring (chemistry) , inorganic chemistry , organic chemistry , medicinal chemistry
[Cp 2 ZrHCl] n was found to be a useful reagent for a number of either ring formation or ring opening reactions involving unsaturated phosphorus compounds. Furthermore, treatment of a variety of phosphorus derivatives with [Cp 2 ZrHCl] n allowed the preparation of several linear or cyclic mono‐, di‐, trior polyphosphanes as well as optically active diphosphanes.