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Phosphorus Analogs of Bipyridines: Their Synthesis and Coordination Chemistry
Author(s) -
Mathey François,
Le Floch Pascal
Publication year - 1996
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19961290303
Subject(s) - chemistry , homoleptic , rhenium , manganese , cationic polymerization , coordination complex , ruthenium , phosphorus , medicinal chemistry , inorganic chemistry , stereochemistry , catalysis , polymer chemistry , organic chemistry , metal
The synthesis and coordination chemistry of 2‐(2‐pyridyl)‐phosphinines and 2,2′‐biphosphinines are reviewed. A noteworthy series of homoleptic complexes of 4,4′,5,5′‐tetramethyl‐2,2′‐biphosphinine (tmbp) with Cr(0), Mo(0), Wo(0) and Ni(0) are described. A [Cu(bpy)(tmbp)] + cationic polymer has been characterized by X‐ray analysis. Ruthenium, manganese and rhenium chelates were also obtained. With Mn 2 (CO) 10 , a (tmbp)‐Mn 2 (CO) 6 complex is formed where tmbp acts as an eight electron donor.