The First Selective Cage Redistribution Reaction of P 4 O 6 | Zendy

Strojek Stephan | Zendy; Jansen Martin | Zendy

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The First Selective Cage Redistribution Reaction of P 4 O 6

Author(s) -

Strojek Stephan,

Jansen Martin

Publication year - 1996

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19961290202

Subject(s) - chemistry , nitrene , cage , adamantane , redistribution (election) , crystallography , molecule , nuclear magnetic resonance spectroscopy , oxygen atom , stereochemistry , infrared spectroscopy , organic chemistry , law , catalysis , mathematics , combinatorics , politics , political science

Reaction of tetraphosphorus hexaoxide with organic azides leads selectively to the cage redistribution products 1 P 4 O 6 NPh, 2 P 4 O 6 NC 2 H 4 Ph, 3 P 4 O 6 NSO 2 CH 3 , 4 P 4 O 6 NC 6 H 13 , and 5 P 4 O 6 NCO 2 C 2 H 5 by nitrene insertion. The molecular structure consists of an adamantane‐like P 4 O 5 N cage with a terminally bound oxygen atom. The P 4 O 5 N cagelike structure is confirmed by 31 P NMR spectroscopy and X‐ray structure analysis. The P 4 O 5 N cages of the P 4 O 6 NR molecules possess a significant geometrical distortion.

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