[Cp 4 Fe 4 (E 2 ) 2 ] Clusters with Triangulated Dodecahedral Fe 4 E 4  Skeletons (E = P, As) | Zendy

Scherer Otto J. | Zendy; Kemény Gunther | Zendy; Wolmershäuser Gotthelf | Zendy

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[Cp 4 Fe 4 (E 2 ) 2 ] Clusters with Triangulated Dodecahedral Fe 4 E 4 Skeletons (E = P, As)

Author(s) -

Scherer Otto J.,

Kemény Gunther,

Wolmershäuser Gotthelf

Publication year - 1995

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19951281202

Subject(s) - dodecahedron , chemistry , crystallography , thermal decomposition , crystal structure , stereochemistry , organic chemistry

The thermolysis of [CpFe(CO) 2 ] 2 ( 1 ) and P 4 or As 4 affords the iron clusters [Cp 4 Fe 4 (E 2 ) 2 ], E = As ( 2a ), P ( 2b ), the Fe 4 E 4 skeleton of which consists of a triangulated dodecahedron. S 8 and gray Se oxidize the P 2 ligands of 2b with formation of [Cp 4 Fe 4 (P 2 X 2 ) 2 ], X = S ( 3a ), Se ( 3b ), complexes with the hitherto unknown P 2 X 2 ligands, 2a, b and 3a, b have been characterized by X‐ray crystallography.

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