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Octacarbonylbis {μ‐(tris(trimethylsilyl)methyl]indany l} dimanganese with Two Monoalkyl Indium Groups Bridging the Mn–Mn Bond
Author(s) -
Uhl Werner,
Keimliling Sven Uwe,
Hiller Wolfgang,
Neumayer Markus
Publication year - 1995
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19951281114
Subject(s) - chemistry , trimethylsilyl , tris , indium , crystal structure , medicinal chemistry , yield (engineering) , molecule , crystallography , stereochemistry , organic chemistry , biochemistry , materials science , metallurgy
Tetrahedra ‐tetrakis[tris(trimethylsilyl)methyl]tetraindane(4) ( 1 ) reacts with decacarbonyldimanganese(0) to yield the bright red crystalline title compound 2 , in which two carbonyl ligands are replaced by two InR fragments. The crystal structure determination of 2 shows two Mn(CO) 4 groups (Mn‐Mn 313.7 pm) bridged by two monoalkylindium units and a planar Mn 2 In 2 molecular center.