Octacarbonylbis {μ‐(tris(trimethylsilyl)methyl]indany l} dimanganese with Two Monoalkyl Indium Groups Bridging the Mn–Mn Bond | Zendy

Uhl Werner | Zendy; Keimliling Sven Uwe | Zendy; Hiller Wolfgang | Zendy; Neumayer Markus | Zendy

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Octacarbonylbis {μ‐(tris(trimethylsilyl)methyl]indany l} dimanganese with Two Monoalkyl Indium Groups Bridging the Mn–Mn Bond

Author(s) -

Uhl Werner,

Keimliling Sven Uwe,

Hiller Wolfgang,

Neumayer Markus

Publication year - 1995

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19951281114

Subject(s) - chemistry , trimethylsilyl , tris , indium , crystal structure , medicinal chemistry , yield (engineering) , molecule , crystallography , stereochemistry , organic chemistry , biochemistry , materials science , metallurgy

Tetrahedra ‐tetrakis[tris(trimethylsilyl)methyl]tetraindane(4) ( 1 ) reacts with decacarbonyldimanganese(0) to yield the bright red crystalline title compound 2 , in which two carbonyl ligands are replaced by two InR fragments. The crystal structure determination of 2 shows two Mn(CO) 4 groups (Mn‐Mn 313.7 pm) bridged by two monoalkylindium units and a planar Mn 2 In 2 molecular center.

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