Metal Complexes with Tetrapyrrole Ligands, LXIX. Facile Synthesis and  13 C‐NMR Spectrum of Dichloro(octaethylporphyrinato)zirconium(IV) | Zendy

Buchler Johann W. | Zendy; Eberle Mike | Zendy

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Metal Complexes with Tetrapyrrole Ligands, LXIX. Facile Synthesis and 13 C‐NMR Spectrum of Dichloro(octaethylporphyrinato)zirconium(IV)

Author(s) -

Buchler Johann W.,

Eberle Mike

Publication year - 1995

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19951281112

Subject(s) - chemistry , tetrapyrrole , zirconium , metal , isocyanide , nuclear magnetic resonance spectroscopy , stereochemistry , organic chemistry , enzyme

The synthesis of dichloro(2,3,7,8,12,13,17,18‐octaethylpor‐phyrinato)zirconium(IV), Zr(oep)Cl 2 , from zirconium tetrachloride and octaethylporphyrin, H 2 (oep), is described. The reported synthesis is a new and simple route to this precursor of organometallic compounds. Zr(oep)Cl 2 was characterized by elemental analyses, 1 H‐ and 13 C‐NMR, UV/Vis, and mass spectra. Hydrolysis yielded a mixture of mono‐ and binuclear hydroxy zirconium(IV) porphyrins.

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