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Metallkomplexe mit biologisch wichtigen Lisganden, LXXXI . Synthese und Kristallstruktur von Rh(I)‐Komplexen mit α‐Aminocarboxylat‐Liganden
Author(s) -
Severin Kay,
Mihan Shahram,
Beck Wolfgang
Publication year - 1995
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19951281111
Subject(s) - chemistry , carboxylate , crystal structure , rhodium , stereochemistry , molecule , hydrogen bond , chelation , x ray crystallography , metal , crystallography , catalysis , diffraction , organic chemistry , physics , optics
Metal Complexes Containing Biologically Important Ligands, LXXX Part LXXX: Ref. . — Synthesis and Crystal Structure of Rhodium(I) Chelates with α‐Amino Carboxylates Part LXXX: Ref. The α‐amino carboxylate complexeswere prepared from Rh(Cl)(CO)(PPh 3 ) 2 and H 2 NC(H)(R)CO 2 in the presence of AgBF 4 and characterized by X‐ray diffraction. In the crystal the complexes form chains by hydrogen bridges between amino and carboxylate groups of adjacent molecules.