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Synthesis and Properties of (Tetra‐ tert ‐butylphthalocyaninato)ruthenium(II) and (Tetra‐ tert ‐butyl‐2,3‐naphthalocyaninato)ruthenium(II)
Author(s) -
Hanack Michael,
Knecht Siegfried,
Polley Rainer
Publication year - 1995
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19951280913
Subject(s) - ruthenium , chemistry , tetra , thermal decomposition , medicinal chemistry , ammonia , organic chemistry , catalysis
The first synthesis of pure tert ‐butyl‐substituted (phthalocyaninato)‐ and (2,3‐naphthalocyaninato)ruthenium [( t Bu) 4 ‐MacRu] by thermal decomposition of ( t Bu) 4 MacRu(L) 2 (L = 3‐chloropyridine, ammonia) is described. The compounds were characterized by UV/Vis, IR, and NMR measurements.
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