Photochemische Reaktionen von Übergangsmetall‐Organyl‐Komplexen mit Olefinen, 13 Photochemisch induzierte [5+2],homo[5+21‐Cycloaddition von 3‐Hexin an Tricarbonyl(η 5 ‐2,4‐cycloheptadien‐l‐yl)mangan | Zendy

Kreiter Cornelius G. | Zendy; Fiedler Christian | Zendy; Frank Walter | Zendy; Reiß Guido J. | Zendy

Premium

Photochemische Reaktionen von Übergangsmetall‐Organyl‐Komplexen mit Olefinen, 13 Photochemisch induzierte [5+2],homo[5+21‐Cycloaddition von 3‐Hexin an Tricarbonyl(η 5 ‐2,4‐cycloheptadien‐l‐yl)mangan

Author(s) -

Kreiter Cornelius G.,

Fiedler Christian,

Frank Walter,

Reiß Guido J.

Publication year - 1995

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19951280513

Subject(s) - chemistry , cycloaddition , manganese , nuclear magnetic resonance spectroscopy , medicinal chemistry , crystal structure , x ray crystallography , transition metal , stereochemistry , photochemistry , crystallography , catalysis , diffraction , organic chemistry , physics , optics

Photochemical Reactions of Transition Metal Organyl Complexes with Olefins, 13 12. Mitteilung: Lit. . – Photochemically Induced [5+2], homo [5+2] Cycloaddition of 3‐Hexyne to Tricarbonyl(η 5 ‐2,4‐cycloheptadien‐1‐yl)manganese Tricarbonyl(η 5 ‐2,4‐cycloheptadien‐1‐yl)manganese ( 1 ) reacts upon UV irradiation in hexane at 243 K with two equivalents of 3‐hexyne ( 2 ) in successive [5+2], homo [5+2] cycloadditions to give tricarbonyl(η 2:2:1 ‐1,2,3,11‐tetraethyltricyclo‐[5.3.1.0 4,10 ]undeca‐2,5‐dien‐11‐yl)manganese ( 3 ). Its crystal and molecular structure was determined by an X‐ray diffraction analysis, in solution it was studied also by IR and NMR spectroscopy.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research