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Synthesis and Structure of the First Dimetalated Diphosphane Disulfide [(η 5 ‐C 5 Me 5 )(CO) 2 FeP(H)(S)] 2
Author(s) -
Weber Lothar,
Misiak Hanns,
Stammler HansGeorg,
Neumann Beate
Publication year - 1995
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19951280419
Subject(s) - chemistry , sulfur , x ray crystallography , disulfide bond , transition metal , spectroscopy , nuclear magnetic resonance spectroscopy , derivative (finance) , elemental analysis , diffraction , stereochemistry , crystallography , medicinal chemistry , inorganic chemistry , organic chemistry , catalysis , biochemistry , physics , quantum mechanics , financial economics , optics , economics
The first transition metal derivative meso ‐[(η 5 ‐C 5 Me 5 )(CO) 2 FeP(H)(S)] 2 ( 2 ) of the unknown diphosphane disulfide [PH 2 (S)] 2 results from treatment of (η 5 ‐C 5 Me 5 )(CO) 2 FePH 2 ( 1 ) with 1.5 equivalents of elemental sulfur. Compound 2 was characterized by means of spectroscopy (IR, 31 P, 31 P{ 1 H}, 13 C{ 1 H}, 1 H NMR) as well as X‐ray diffraction analysis.
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