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Darstellung und Struktur von Allyl(tripod)cobalt(I) und der Vergleich zum analogen Cobalt(II)‐Komplex
Author(s) -
Sernau Volker,
Huttner Gottfried,
Scherer Johannes,
Zsolnai Laszlo,
Seitz Thomas
Publication year - 1995
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19951280218
Subject(s) - tripod (photography) , cobalt , chemistry , cationic polymerization , stereochemistry , medicinal chemistry , polymer chemistry , inorganic chemistry , physics , optics
Preparation and Structure of Allyl(tripod)cobalt(I) and the Comparison with the Analogous Cobalt(I) Complex The synthesis of the 18‐electron diamagnetic allyl(tripod)cobalt(I) complex [{CH 3 C(CH 2 PPh 2 ) 3 }Co(η 3 ‐C 3 H 5 )] ( 1 ) is presented. Its structure is established by the usual analytical techniques as well as by X‐ray analysis, and it is proved to be significantly different from that of the cationic 17‐electron species 1 + .