Darstellung und Struktur von Allyl(tripod)cobalt(I) und der Vergleich zum analogen Cobalt(II)‐Komplex | Zendy

Sernau Volker | Zendy; Huttner Gottfried | Zendy; Scherer Johannes | Zendy; Zsolnai Laszlo | Zendy; Seitz Thomas | Zendy

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Darstellung und Struktur von Allyl(tripod)cobalt(I) und der Vergleich zum analogen Cobalt(II)‐Komplex

Author(s) -

Sernau Volker,

Huttner Gottfried,

Scherer Johannes,

Zsolnai Laszlo,

Seitz Thomas

Publication year - 1995

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19951280218

Subject(s) - tripod (photography) , cobalt , chemistry , cationic polymerization , stereochemistry , medicinal chemistry , polymer chemistry , inorganic chemistry , physics , optics

Preparation and Structure of Allyl(tripod)cobalt(I) and the Comparison with the Analogous Cobalt(I) Complex The synthesis of the 18‐electron diamagnetic allyl(tripod)cobalt(I) complex [{CH 3 C(CH 2 PPh 2 ) 3 }Co(η 3 ‐C 3 H 5 )] ( 1 ) is presented. Its structure is established by the usual analytical techniques as well as by X‐ray analysis, and it is proved to be significantly different from that of the cationic 17‐electron species 1 + .

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