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Übertragung eines cyclo ‐E 5 ‐Liganden (E P, As) von einem Eisen‐ auf ein Ruthenium‐ und ein Osmium‐Zentrum
Author(s) -
Rink Barbara,
Scherer Otto J.,
Wolmershäuser Gotthelf
Publication year - 1995
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19951280110
Subject(s) - osmium , chemistry , ruthenium , crystal structure , ligand (biochemistry) , thermal decomposition , center (category theory) , crystallography , stereochemistry , catalysis , organic chemistry , biochemistry , receptor
Transfer of a cyclo ‐E 5 Ligand (E P, As) from an Iron to a Ruthenium and an Osmium Center ☆ The thermolysis of [Cp*Fe(η 5 ‐E 5 )] ( 1 ) and [{Cp*M(CO) 2 } 2 ] ( 2, 3 ) affords by cyclo ‐E 5 transfer the sandwich complexes [Cp* M(η 5 ‐E 5 )] ( 4a, b : M Ru, E P, As; 4c : M Os, E P). The crystal‐structure analysis of [(C 5 Me 4 Et)Os(η 5 ‐P 5 )] ( 4c ') confirms its sandwich‐type structure.