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Oxidationsreaktionen mit HOF sowie Addukte von HOF und HF mit Acetonitril
Author(s) -
Dunkelberg Oliver,
Haas Alois,
Klapdor Martin Frank,
Mootz Dietrich,
Poll Wolfgang,
Appelman Evan Hugh
Publication year - 1994
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19941271009
Subject(s) - chemistry , acetonitrile , adduct , medicinal chemistry , yield (engineering) , organic chemistry , metallurgy , materials science
Oxidation Reactions with HOF and Adducts of HOF and HF with Acetonitrile In acetonitrile solution HOF oxides CF 3 SSCF 3 via CF 3 S(O) n SCF 3 ( n = 1, 2) to yield [CF 3 S(O) 2 ] 2 O. Analogously, CF 3 Se(O)OH and CF 3 SeX (X = Cl, Br) are oxidized via CF 3 Se(VI) intermediates to provide finally [CF 3 Se(O) 2 ] 2 O. With CH 3 CN at low temperatures HOF and HF form 1:1 adducts, whose structures have been elucidated by low‐temperature X‐ray structure analysis. Additional proof for the formation of CH 3 CN · HF in the liquid phase is provided.