Synthesis and Structure of the New α‐Aminosilanolate [LiOSiMe 2 (NMe 2 )] 6 | Zendy

Herberich Gerhard E. | Zendy; Spaniol Thomas P. | Zendy; Fischer Andreas | Zendy

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Synthesis and Structure of the New α‐Aminosilanolate [LiOSiMe 2 (NMe 2 )] 6

Author(s) -

Herberich Gerhard E.,

Spaniol Thomas P.,

Fischer Andreas

Publication year - 1994

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19941270912

Subject(s) - chemistry , random hexamer , lithium (medication) , crystallography , yield (engineering) , hexagonal crystal system , molecule , crystal structure , ion , symmetry (geometry) , stereochemistry , organic chemistry , geometry , physics , medicine , mathematics , endocrinology , thermodynamics

Lithium (dimethylamino)dimethylsilanolate ( 1 ) is obtained from trimeric dimethylsiloxane and lithium dimethylamide in quantitative yield. In the crystal 1 is a hexamer [LiOSiMe 2 (NMe 2 )] 6 with crystallograpic C 3 i ( S 6 , 3) symmetry. The molecule of 1 consists of a hexagonal prismatic (LiO) 6 core and an N,O ‐chelating anion.

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