Derivate des Imidazols, XI. (C 8 H 14 N 2 )M(CO) 5  (M = Mo, W) ‐ Terminale Koordination eines Olefins in Pentacarbonylmetall‐Komplexen | Zendy

Kuhn Norbert | Zendy; Bohnen Hans | Zendy; Bläser Dieter | Zendy; Boese Roland | Zendy

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Derivate des Imidazols, XI. (C 8 H 14 N 2 )M(CO) 5 (M = Mo, W) ‐ Terminale Koordination eines Olefins in Pentacarbonylmetall‐Komplexen

Author(s) -

Kuhn Norbert,

Bohnen Hans,

Bläser Dieter,

Boese Roland

Publication year - 1994

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19941270814

Subject(s) - chemistry , olefin fiber , ligand (biochemistry) , imidazole , metal , stereochemistry , group 2 organometallic chemistry , medicinal chemistry , crystallography , molecule , catalysis , organic chemistry , biochemistry , receptor

Imidazole Derivatives, XI. ‐ (C 8 H 14 N 2 )M(CO) 5 (M = Mo, W) ‐ Terminal Coordination of an Olefin in Pentacarbonyl Metal Complexes Herrn Professor Reinhard Schmutzler zum 60. Geburtstag gewidmet. The 2‐methylenimidazoline complexes (C 8 H 14 N 2 )M(CO) 5 (M = Mo, W; 6 ) are obtained from M(CO) 6 and 1,3,4,5‐tetramethyl‐2‐methyleneimidazoline ( 5 ). Spectroscopic data reveal the strong donor character of the ylidic ligand in 6 . The end‐on coordination mode of the olefin is demonstrated by an X‐ray structure analysis of 6a .

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