Transition Metal Chemistry of Main Group Hydrazides, 9. Platinum Complexes of Diphosphanylhydrazides R 2 PN(Me)N(Me)PR 2  · PtCl 2  (R = OPh,  o ‐OC 6 H 4 CH 2 CHCH 2 ) | Zendy

Sreenivasa Reddy V. | Zendy; Katti Kattesh V. | Zendy; Barnes Charles L. | Zendy

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Transition Metal Chemistry of Main Group Hydrazides, 9. Platinum Complexes of Diphosphanylhydrazides R 2 PN(Me)N(Me)PR 2 · PtCl 2 (R = OPh, o ‐OC 6 H 4 CH 2 CHCH 2 )

Author(s) -

Sreenivasa Reddy V.,

Katti Kattesh V.,

Barnes Charles L.

Publication year - 1994

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19941270805

Subject(s) - chemistry , transition metal , stereochemistry , crystallography , metal , group (periodic table) , medicinal chemistry , organic chemistry , catalysis

While the transition metal complexes of bis(phosphanyl)amines (P II ‐N‐P III ) have been known for over three decades, the ligating properties of the next homologue P III ‐N‐N‐P III have been unprecedented so far. The X‐ray structures of cycloplatinaphosphanehydrazides, [(OR) 2 PN(Me)N(Me)P(OR) 2 ‐PtCl 2 ], reveal short distances for the P‐N [1.639(5) Å] bonds.

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