Premium
Transition Metal Chemistry of Main Group Hydrazides, 9. Platinum Complexes of Diphosphanylhydrazides R 2 PN(Me)N(Me)PR 2 · PtCl 2 (R = OPh, o ‐OC 6 H 4 CH 2 CHCH 2 )
Author(s) -
Sreenivasa Reddy V.,
Katti Kattesh V.,
Barnes Charles L.
Publication year - 1994
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19941270805
Subject(s) - chemistry , transition metal , stereochemistry , crystallography , metal , group (periodic table) , medicinal chemistry , organic chemistry , catalysis
While the transition metal complexes of bis(phosphanyl)amines (P II ‐N‐P III ) have been known for over three decades, the ligating properties of the next homologue P III ‐N‐N‐P III have been unprecedented so far. The X‐ray structures of cycloplatinaphosphanehydrazides, [(OR) 2 PN(Me)N(Me)P(OR) 2 ‐PtCl 2 ], reveal short distances for the P‐N [1.639(5) Å] bonds.