Komplexe mit makrocyclischen Liganden, II. Synthese, Struktur und elektrochemische Eigenschaften eines makrocyclischen Cu 2  II Mn II ‐Komplexes vom Schiff‐Basen‐Typ | Zendy

Brychcy Klaus | Zendy; Jens KlausJ. | Zendy; Tilset Mats | Zendy; Behrens Ulrich | Zendy

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Komplexe mit makrocyclischen Liganden, II. Synthese, Struktur und elektrochemische Eigenschaften eines makrocyclischen Cu 2 II Mn II ‐Komplexes vom Schiff‐Basen‐Typ

Author(s) -

Brychcy Klaus,

Jens KlausJ.,

Tilset Mats,

Behrens Ulrich

Publication year - 1994

Publication title -

chemische berichte

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.667

H-Index - 136

eISSN - 1099-0682

pISSN - 0009-2940

DOI - 10.1002/cber.19941270605

Subject(s) - chemistry , schiff base , electrochemistry , crystallography , copper , ligand (biochemistry) , x ray crystallography , stereochemistry , molecule , sandwich compound , polymer chemistry , diffraction , biochemistry , physics , receptor , organic chemistry , electrode , optics

Complexes with Macrocyclic Ligands, II. — Synthesis, Structure and Electrochemical Properties of a Macrocyclic Cu 2 IIMn II Complex of Schiff Base Type A novel trinuclear Cu 2 Mn complex 4 of a macrocyclic Schiff base ligand obtained by condensation of 5‐ tert ‐butyl‐2‐hydroxy‐1,3‐benzenedicarbaldehyde with 1,2‐phenylenediamine was synthesized. The molecular structure of 4 was determined by X‐ray diffraction revealing a sandwich‐type structure as depicted by Figure 2. Electrochemical investigations (DCV measurements) showed two one‐electron reduction steps for the copper ions at E 1/2 = ‐1.383 and ‐1.652 V (vs. Cp 2 Fe/Cp 2 Fe + ).

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