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Chirale Lactole, XI. Eine Methode zur Bestimmung der Absolutkonfiguration chiraler Alkanole
Author(s) -
Noe Christian R.,
Knollmüller Max,
Miculka Christian,
Dungler Karin,
Wagner Ernst,
Ettmayer Peter
Publication year - 1994
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19941270516
Subject(s) - chemistry , absolute configuration , lactol , absolute (philosophy) , stereochemistry , glycosidic bond , chirality (physics) , hemiacetal , organic chemistry , lactone , chiral symmetry , philosophy , quantum mechanics , enzyme , quark , nambu–jona lasinio model , physics , epistemology
Chiral Lactols, XI. ‐ A Method for the Determination of the Absolute Configuration of Chiral Alkanols Chiral secondary alcohols which are protected with the enantiomerically pure lactol 1 or 2 show significant differences in 13 C‐chemical shifts around the glycosidic linkage. An easy method for determination of the absolute configuration of secondary alcohols based on this fact is described.