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Zur Thermolyse von Amin— arachno ‐Nonaboran
Author(s) -
Meyer Franc,
Englert Ulli,
Paetzold Peter
Publication year - 1994
Publication title -
chemische berichte
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.667
H-Index - 136
eISSN - 1099-0682
pISSN - 0009-2940
DOI - 10.1002/cber.19941270512
Subject(s) - chemistry , diethylamine , deprotonation , amine gas treating , thermal decomposition , medicinal chemistry , decaborane , amidine , zwitterion , molecule , ion , organic chemistry , boron
On the Thermolysis of Amine‐ arachno ‐Nonaborane Two molecules of diethylamine‐ arachno ‐nonaborane, B 9 H 13 ‐(NHEt 2 ), undergo a condensation at 140°C to give diethylamine‐ conjuncto ‐bis[6′,5′:5,6]decaborane, B 18 H 20 (NHEt 2 ) (4). The deprotonation of 4 yields the anion [B 18 H 19 (NHEt 2 )]‐which can be crystallized with the cation [NEt 3 (CH 2 Ph)] + (space group P 1).